The content of natural radionuclides Ra226, Th232, K40 in titanium ores and host rocks of the Pizhemskoye deposit
https://doi.org/10.32454/0016-7762-2022-64-2-39-46
Abstract
Background. The value of natural radionuclide content in ores is a fundamental characteristic of any ore deposit, determining the possibility of studying, developing and enriching these ores, as well as manufacturing commercial products on their basis.
Aim. To evaluate the content of natural radionuclides in the rocks and ores of the Pizhem titanium deposit and to determine their mineral concentrators.
Materials and methods. A study of 15 core samples from wells within the Pizhem titanium deposit was carried out in the laboratories of IGEM RAS and VIMS using an “Ortec-65195-P/DSPecPlus” semiconductor gamma spectrometer.
Results. For the first time, a radiation safety assessment was carried out and the concentration of Ra226, Th232 and K40 natural radionuclides in the titanium ores and host rocks of the Pizhemskoye deposit (the Middle Timan) was determined. The mineral concentrators for Ra226, Th232 and K40 were found to be zircon, monazite (kularite) and hydromuscovite-illite, respectively. The lowest content of radionuclides was established for quartz (D2pz) and quartz-kaolinite (PR3mr3) sandstones of glass quality. The titanium ores of the deposit belong to the I class of mineral raw materials (Aeff < 0.74 kBq/kg), thereby being completely harmless to humans.
Conclusion. The low content of radionuclides in the studied ores allows them to be safely enriched, and the overburden sandstones of glass quality to be used without restrictions.
Keywords
About the Author
A. B. MakeyevRussian Federation
Alexander B. Makeyev — Dr. of Sci. (Geol. and Mineral.), Leading Researcher; Professor in Mineralogy and Crystallography
35, Staromonetny Lane, Moscow 119017
SPIN-code: 6640-1703
References
1. Kontarovich R.S. Report on aerogeophysical searches for bauxite and other solid minerals on the Pizhmenskaya and Volsko-Vymskaya areas of Timan by party No. 36 in 1977—78, 1979. Rosgeolfond (In Russian).
2. Makeyev A.B. Typomorphic features of minerals of titanium ores of the Pizhemskoye deposit // Mineralogiya. 2016. No 1. P. 24—49 (In Russian).
3. Makeyev A.B. The Pizhemskoye titanium deposit is a new object of the nearest development in the Arctic zone of Russia] // Arktika: ekologiya i ekonomika. [Arctic: Ecology and Economy. 2021. V. 11. No 4. P. 541—556 (In Russian). https://doi.org/10.25283/2223-4594-2021-4-541-556
4. Makeyev A.B., Borisovskiy S.E., Krasotkina A.O. The chemical composition and age of monazite and kularite from titanium ore of Pizhemskoye and Yarega deposits (Middle and Southern Timan) //Georesources. 2020. V. 22. No 1. P. 22—31 (In Russian). https://doi.org/10.18599/grs.2020.1.22-31
5. Makeyev A.B., Viryus A.A. Monazit of the Ichetyu occurrence (composition, morphology, age) // Proceedings of higher educational establishments. Geology and Exploration. 2013. No 3. P. 10—15 (In Russian).
6. Makeyev A.B., Krasotkina A.O., Skublov S.G. Geochemistry and U-Pb-age of zircon from Pizhemskoe titanium deposit (Middle Timan) //Vestnik IG Komi SC UB RAS. 2016. No 5. P. 38—52 (in Russian). https://doi.org/10.19110/2221-1381-2016-5-38-52
7. Makeyev A.B., Krasotkina A.O., Skublov S.G. New data on the U-Pb age and composition of zircon (SHRIMPII, SIMS) from the Ichetyu polymineral ore occurrence (Middle Timan) //Vestnik IG Komi SC UB RAS. 2017. No 11. P. 28—42 (In Russian). https://doi.org/10.19110/2221-1381-2017-11-28-42
8. Makeyev A.B., Krasotkina A.O., Skublov S.G. Clay shales of the Lunvozhskaya formation of the Volsko-Vymskaya ridge (Middle Timan): composition, age, accessory zircon. Materials of the Mineralogical seminar with international participation “Modern problems of theoretical, experimental and applied mineralogy” (Yushkin readings — 2018). Syktyvkar, 2018, P. 40—41 (In Russian).
9. Makeyev A.B., Makeyev B.A., Borisovskiy S.E. Thorium phosphate: New mineral phase (Middle Timan, Komi Republic) // Regional Geology and Metallogeny. 2021. No. 87. P. 110—117 (In Russian). https://doi.org/10.52349/0869-7892_2021_87_110-117
10. Makeyev A.B. and Skublov S.G. Y-REE-Rich Zircons of the Timan Region: Geochemistry and Economic Significance // Geochemistry International, 2016, V. 54. No 9. P. 788—794. https://doi.org/10.1134/S0016702916080073
11. Makeyev A.B., Skublov S.G., Krasotkina A.O., Borisovskiy S.E., Thomsen T.B., Serre S.H. The age of monazite from the Ichet’yu occurrence, Middle Timan (Chime and LA—ICP—MS Methods) // Geology of Ore Deposits. 2020. V. 62. No 8. P. 773—786. https://doi.org/10.1134/S1075701520080103
12. Application. Sanitary rules and regulations SanPiN 2.6.1.2523-09 “Norms of radiation safety NRB99/2009” (approved by the resolution of the Chief State Sanitary Doctor of the Russian Federation dated July 7, 2009. No 47) (In Russian).
13. Radiation control and sanitary-epidemiological assessment of mineral fertilizers and agrochemicals according to radiation safety indicators. Moscow: Federal Center for Hygiene and Epidemiology of Rospotrebnadzor. 2014. 20 p. (In Russian).
14. Tigunov L.P., Bykhovsky L.Z., Zubkov L.B. Titanium ores of Russia: state and prospects of development, in Mineral Raw Materials, Geological and Economic Series. Ed. by L.P. Tigunov, (VIMS, Moscow, 2005). No. 17. 104 p. (in Russian).
Review
For citations:
Makeyev A.B. The content of natural radionuclides Ra226, Th232, K40 in titanium ores and host rocks of the Pizhemskoye deposit. Proceedings of higher educational establishments. Geology and Exploration. 2022;(2):39-46. (In Russ.) https://doi.org/10.32454/0016-7762-2022-64-2-39-46