Impact assessment of mineralization and cation exchange capacity on the resistivity index of clayey sandstones on the example of cretaceous deposits in Western Siberia
https://doi.org/10.32454/0016-7762-2025-67-4-30-38
Abstract
Background. The validity of initial deposit assessment largely depends on the accuracy of water saturation determination. The saturation exponent (n) is an important parameter included in the majority of generally accepted integrated models for determining water saturation. The error of saturation determination at the level of 0.5 may distort the final estimate of water saturation by 30%. It is believed that the Resistivity Index (RI) is affected not only by the coefficient of current water saturation (Sw) but also by such factors as wettability, reservoir water mineralization and its ionic composition, as well as the amount and mineral composition of clays.
Aim. To assess the effect of cation exchange capacity and mineralization on the saturation exponent of Cretaceous clayey rocks from a Western Siberian field. Materials and methods. The research objects were 23 core samples alternately saturated with model formation water of different mineralization and composition. The samples were collected from Cretaceous deposits in a Western Siberian field located in the Middle Ob oil-gas area. The experiments were conducted in the modes of full and partial water saturation.
Results. The influence of cation exchange capacity, as well as the mineralization and composition of the model formation water, on the saturation exponent is absent. No change was found in the effect of ‘bound’ water on the rock conductivity depending on changes in the current water saturation.
Conclusion. Knowledge of the influence of the mineralization and composition of reservoir water, as well as cation exchange capacity, on the Resistivity Index is important for assessing the risks of inaccurate determination of saturation exponent (n) during standard laboratory studies using sodium chloride models of reservoir water of a single mineralization.
About the Authors
I. V. MotorinRussian Federation
Ivan V. Motorin — Senior specialist
75—79, Moika River emb., 190000, Saint Petersburg
tel.: +7 (985) 305-81-61
Competing Interests:
the authors declare no conflict of interest
E. O. Belyakov
Russian Federation
Evgeniy O. Belyakov — Cand. Sci. (Geol.-Mineral.), Leader of the Petrophysical discipline development
RINC Author ID: 273304
75—79, Moika River emb., 190000, Saint Petersburg
Competing Interests:
the authors declare no conflict of interest
D. V. Velesov
Russian Federation
Daniil V. Velesov — Chief specialist
75—79, Moika River emb., 190000, Saint Petersburg
Competing Interests:
the authors declare no conflict of interest
References
1. Vendelshtein B.Yu. On the relationship between porosity parameter, surface conductivity coefficient, diffusion-adsorptive activity, and adsorptive properties of terrigenous rocks. Moscow: Gostoptekhizdat, 1960. Issue 31. (In Russ.)
2. Voitkevich G.V., Miroshnikov A.E., Povarenykh A.S., Prokhorov V.G. Concise Handbook of Geochemistry. 2nd–3rd ed., revised and expanded. Moscow: Nedra, 1977 (In Russ.).
3. Dakhnov V.N. Geophysical Methods for Determining Reservoir Properties and Oil-Gas Saturation of Rocks. 2nd ed., revised and expanded. Moscow: Nedra, 1985. 311 p. (In Russ.).
4. Motorin I.V., Belyakov E.O., Petrophysical modeling of water saturation based on experiments of measuring electrical conductivity in different water saturation regimes with different mineralization (In Russ.), Neftyanoe khozyaystvo = Oil Industry, 2025, No. 4, pp. 54—58 (In Russ.). DOI: 10.24887/0028-2448-2025-4-54-58
5. Sokolova T.A., Trofimov S.Ya. Adsorptive Properties of Soils. Adsorption. Cation Exchange: Textbook on Selected Chapters of Soil Chemistry. Tula: Grif and Co., 2009. 172 p. (In Russ.).
6. Filippov A.V., Starov V.M. Electrostatic and van der Waals Interactions of Nanoparticles in Electrolytes. JETP Letters. 2023, Vol. 117, No. 8, pp. 604—611 (In Russ.). DOI: 10.1134/S0021364023080056
7. Frolov Yu.G. Course of Colloid Chemistry (Surface Phenomena and Disperse Systems): Textbook for Universities. Moscow: Khimiya, 1982. 400 p. (In Russ.).
8. Anderson W.G. Wettability literature survey. Part 3: the effects of wettability on the electrical properties of porous media. SPE Journal of Petroleum Technology. 1986. Vol. 38, no. 12. P. 1371—1378 (In Russ.). DOI: 10.2118/13771-PA
9. Clavier C., Coates G., Dumanoir J. Theoretical and experimental bases for the Dual-Water model for interpretation of Shaly Sands. SPE Journal. 1984. Vol. 24, no. 2. P. 153—168. DOI: 10.2118/6859-PA
10. Waxman M.H., Smits L.J.M. Electrical conductivities in oil-bearing shaly sands. Society of Petroleum Engineers Journal. 1968. Vol. 8, no. 2. P. 107—122.
11. Worthington P.E. The evolution of shaly-sand concepts in reservoir evaluation. Log Analyst. 1985. Vol. 26, no. 1. P. 23—40.
Review
For citations:
Motorin I.V., Belyakov E.O., Velesov D.V. Impact assessment of mineralization and cation exchange capacity on the resistivity index of clayey sandstones on the example of cretaceous deposits in Western Siberia. Proceedings of higher educational establishments. Geology and Exploration. 2025;67(4):30-38. (In Russ.) https://doi.org/10.32454/0016-7762-2025-67-4-30-38

































